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11.
This study analyzes the economics of transshipping biomass from truck to train in a North American setting. Transshipment
will only be economic when the cost per unit distance of a second transportation mode is less than the original mode. There
is an optimum number of transshipment terminals which is related to biomass yield. Transshipment incurs incremental fixed
costs, and hence there is a minimum shipping distance for rail transport above which lower costs/km offset the incremental
fixed costs. For transport by dedicated unit train with an optimum number of terminals, the minimum economic rail shipping
distance for straw is 170 km, and for boreal forest harvest residue wood chips is 145 km. The minimum economic shipping distance
for straw exceeds the biomass draw distance for economically sized centrally located power plants, and hence the prospects
for rail transport are limited to cases in which traffic congestion from truck transport would otherwise preclude project
development. Ideally, wood chip transport costs would be lowered by rail transshipment for an economically sized centrally
located power plant, but in a specific case in Alberta, Canada, the layout of existing rail lines precludes a centrally located
plant supplied by rail, whereas a more versatile road system enables it by truck. Hence for wood chips as well as straw the
economic incentive for rail transport to centrally located processing plants is limited. Rail transshipment may still be preferred
in cases in which road congestion precludes truck delivery, for example as result of community objections. 相似文献
12.
J. C. Raines J. P. Schmidt J. P. Burelbach H. K. Fauske 《Journal of Thermal Analysis and Calorimetry》2006,85(1):53-55
Hydrogen
peroxide is a very versatile oxidizing agent, and it is also environmentally
compatible considering that the products of its exothermic decomposition are
oxygen and water.When kept in a clean temperature-controlled environment,
the self-reaction (decomposition) rate is extremely low. However, it is well
known that even a small amount of contamination will dramatically increase
the reaction rate. This paper describes the use of the fast thermal activity
interpreter (FTAI) instrument to examine the chemical reactivity of commercially
available 50% hydrogen peroxide at two different temperatures (30 and 40°C)
both with and without contamination. The results show that at 30°C a small
amount of rust (330 ppm) increases the reaction rate of 50% hydrogen peroxide
by a factor of 50. When the temperature is increased to 40°C, the reaction
rate is further increased by almost a factor of four. The implication for
reactivity management is that at this contamination level most practical vessel
sizes would require emergency venting capability.
An evaluation
was then performed to determine the emergency venting requirement for the
safe transportation or storage of the contaminated hydrogen peroxide. It was
determined that for quantities of the material less than 5 gallons, conventional
breather vents would be sufficient to accommodate the gas evolved. However,
for larger quantities, a safety relief device would be needed. For example,
for a 400-gallon tote bin at 40°C the required minimum vent area is estimated
to be 4.3 in2, corresponding to a minimum vent
diameter of 2.3 inches. 相似文献
13.
Liquid chromatography-electrospray ionisation mass spectrometry was evaluated in the high-throughput analysis of microcystins and nodularins, cyanobacterial peptide hepatotoxins. Extracts originating from cyanobacterial strains and field material were separated on a 30 mm × 4 mm I.D. Merck Purospher STAR RP-18e column using a rapid gradient of aqueous formic acid and acetonitrile, ionised by electrospray technique and analysed on a Micromass Quattro II triple-quadrupole mass spectrometer operated in the selected ion recording (SIR) mode. The total analysis time per sample was 2.8 min corresponding to 514 samples a day. The system showed good robustness during a series of 320 repetitive injections of a field sample containing three major microcystins. 相似文献
14.
We start with a stochastic flow of diffeomorphisms of the space. Particles enter the space at random times and places. Each particle is carried by the flow for some random amount of time. We examine the point process formed by the particles at a fixed time, on the evolution of that point process as time varies, and on the equilibrium law of the point process. 相似文献
15.
T. A. Berger 《Journal of separation science》1989,12(2):96-100
A model for restrictor flow produces accurate predictions of flow that can be used to optimize restrictor design. The relative amplitudes of restrictor and other flows and their effect on efficiency are discussed. 相似文献
16.
17.
《Electroanalysis》2005,17(3):255-262
Characteristics of mass transport and potential distribution applicable to microfluidic electrochemical flow cell devices has been modelled using the finite element method. A flexible, automatic grid generation algorithm has been combined with an a‐posteriori error indication technique presented by Nann and Heinze to allow irregular cell geometries to be modelled. The code has been applied to the problem of steady state generator – detector linear sweep voltammetry in a channel flow cell showing the effects of IR drop on the voltammetric response of each electrode. 相似文献
18.
以美国南弗洛里达州递避飓风袭击为例建立了紧急输送情况下的线性规划模型。其中具体建立了以SCEPD(美国南弗洛里达州紧急情况预防部门)提出的公路反向,地区分块撤离,使用小路等三个最受人们关注的策略的模型。模型的灵敏度分析能很好地解释建立更多的临时避难所、限制车辆等策略对撤离的影响。在相近的环境下,中模型解得的结果很接近官方预测的结果,并且本的模型能对更广泛的情况进行分析.可给SCEPD提供一定参考。 相似文献
19.
F. Berthelin F. Bouchut 《Annales de l'Institut Henri Poincaré (C) Analyse Non Linéaire》2003,20(6):189-997
We consider isentropic gas dynamics equations with unilateral constraint on the density and mass loss. The γ and pressureless pressure laws are considered. We propose an entropy weak formulation of the system that incorporates the constraint and Lagrange multiplier, for which we prove weak stability and existence of solutions. The nonzero pressure model is approximated by a kinetic BGK relaxation model, while the pressureless model is approximated by a sticky-blocks dynamics with mass loss. 相似文献
20.
Seventeen 1-aryl-2,2-dichlorocyclopropanes were examined by using IR, 13C NMR, and mass spectrometry. The data obtained from IR and 13C NMR spectra indicate that the bond strength of carbon-chlorine on the cyclopropane ring and the electron density of that carbon depend on the substituent. The mass fragmentation patterns of compounds in this series resemble those of the dibromo analogues. The fragmentation mechanism is proposed to involve the formation of indenium ion through an electrocyclization. 相似文献